Chocolate v cocoa
When buying chocolate, don't bother buying the fancy stuff, or even cooking chocolate (unless you have a large disposable income). I buy the massive slabs of Old Gold, those babies will last you 2-3 batches. Whatever you end up getting, just make sure it has about 70% cocoa.
Sugar
Sugar is great isn't it? Well, no. Not really. The main change I make to my recipes is to reduce the amount of sugar, there's already almost enough in the chocolate. Generally in my recipes, if I've put 3/4, it was probably a cup to begin with etc. etc.

As a rule, any nuts are better than no nuts (isn't that the rule for pretty much everything?). My favourites are walnuts because they're soft and lower in fat, although that's a minor concern. I also use almonds a lot, pecans when I must and macadamias if I'm using white chocolate/suddenly get a sugar daddy.
Baking Paper
The last awesome little tip is from Jamie's 30 minute meals. Baking paper is a must when baking brownies, given the vast amount of sugar. The best way to fit it into the tin is to crumple a good-sized sheet and wet it completely, then squeeze excess water out. This makes it really easy to handle & easy to get into the corners of the pan. Neat huh?
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